X-Ray diffraction study of the title compound has shown that [Pt2(µ-Ph2PCH2)3] adopts a ‘manxane’-type (bicyclo[3.3.3]undecane-type) structure, with trigonal planar co-ordination of the platinum atoms and approximate C3h molecular symmetry.
L. Manojlović-Muir and K. W. Muir, J. Chem. Soc., Chem. Commun., 1982, 1155 DOI: 10.1039/C39820001155
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