Decomposition of azidoacrylates (2) derived from 2-alkylindole-3-carbaldehydes gives pharmacologically important β-carboline derivatives [(4), (5)], or azepino[4,5-b]indoles (6) in a new reaction of vinyl azides.
C. J. Moody and J. G. Ward, J. Chem. Soc., Chem. Commun., 1982, 1148 DOI: 10.1039/C39820001148
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