A new route to the pavine skeleton was investigated starting from the readily accessible tetrahydro-6,12-methanodibenz[c,f]azocine (1,R![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
H or Me); an efficient synthesis of a typical pavine alkaloid (±)-argemonine (6, R = OMe) from (1, R = OMe) was accomplished in 53% overall yield.
T. Nomoto and H. Takayama, J. Chem. Soc., Chem. Commun., 1982, 1113 DOI: 10.1039/C39820001113
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