Issue 18, 1982

Tertiary phosphine adducts of manganese(II) dialkyls: synthesis and X-ray crystal structure of bis(trimethylphosphine)bis(trimethylsilylmethyl)bis(µ-trimethylsilylmethyl)dimanganese(II)

Abstract

The interaction of PMe3 with [Mn(CH2SiMe3)2]n gives Mn2(CH2SiMe3)4(PMe3)2, the frist crystallographically characterised unidentate phosphine complex of manganese(II).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 1077-1078

Tertiary phosphine adducts of manganese(II) dialkyls: synthesis and X-ray crystal structure of bis(trimethylphosphine)bis(trimethylsilylmethyl)bis(µ-trimethylsilylmethyl)dimanganese(II)

J. I. Davies, C. G. Howard, A. C. Skapski and G. Wilkinson, J. Chem. Soc., Chem. Commun., 1982, 1077 DOI: 10.1039/C39820001077

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