Carbon–Carbon bond formation via electrochemical coupling of diazoalkane ligands has been investigated; one-electron reduction of trans-[WF(N2CH2)L2]+ in a MeCN electrolyte at a Hg pool cathode affords [L2FW{N2CH2CH2N2}WFL2] in moderate yield (L = Ph2PCH2CH2PPh2).
C. J. Pickett, J. E. Tolhurst, A. Copenhaver, T. A. George and R. K. Lester, J. Chem. Soc., Chem. Commun., 1982, 1071 DOI: 10.1039/C39820001071
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