Above 0 °C in various solvents the complexes cis-[PtH(SiR3)(PPh3)2] with R = C6H5, p-ClC6H4, or p-MeC6H4 undergo spontaneous interchange of the PPh3 ligand position by a mechanism which retains P ⋯(Pt)⋯ H spin correlation and is thus intramolecular and non-dissociative within the limits of the n.m.r. experiment.
H. Azizian, K. R. Dixon, C. Eaborn, A. Pidcock, N. M. Shuaib and J. Vinaixa, J. Chem. Soc., Chem. Commun., 1982, 1020 DOI: 10.1039/C39820001020
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