The mononuclear complexes W(CO)5L (L = MeSCH2Sme, MeSeCH2SeMe, and MeSCH2SeMe) possess a noval floxional character which from dynamic n.m.r. studies may be interpreted as intramolecular 1,3-metal jumps between ligand atoms; and indication of the relative strengths of the S → W and Se → W bonds is obtained from these studies.
E. W. Abel, S. K. Bhargava, T. E. MacKenzie, P. K. Mittal, K. G. Orrell and V. Šik, J. Chem. Soc., Chem. Commun., 1982, 983 DOI: 10.1039/C39820000983
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