2-Diazo-1,3-dimesityl-2H-indene (2) is prepared by reaction of 2-amino-1,3-dimesityl-2H-indene with sodium nitrite–acetic acid; though isolable (2) decomposes either thermally (20 ° C) or on exposure to visible light to give the hydrocarbons (6), (7), and (8) derived via the carbene (9) and the o-quinodimethane (10).
D. W. Jones and A. Pomfret, J. Chem. Soc., Chem. Commun., 1982, 919 DOI: 10.1039/C39820000919
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