Rubrofusarin biosynthesis in Fusarium culmorum: incorporation of 13CH313CO2H and CD313CO2H into the polyketide naphthalene nucleus
Abstract
The pattern of chain-folding in the linear polyketide precursor of the naphtalene nucleus of rubrofusarin has been determined by the standard technique using 13CH313CO2H and by the β-shift technique using CD313CO2H.