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Issue 15, 1982
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(CH2LiF)2: the effect of dimerization on the structure and dissociation energy of carbenoids

Abstract

Ab initio molecular orbital theory suggests that the non-tetrahedral structural features of the prototype carbenoid, CH2LiF, are retained in its dimer; however, dissociation of singlet methylene is thermodynamically much more favourable from the dimer than from the monomer.

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Article information


J. Chem. Soc., Chem. Commun., 1982, 882-884
Article type
Paper

(CH2LiF)2: the effect of dimerization on the structure and dissociation energy of carbenoids

C. Rohde, T. Clark, E. Kaufmann and P. von Ragué Schleyer, J. Chem. Soc., Chem. Commun., 1982, 882
DOI: 10.1039/C39820000882

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