In the exchange of solvent water with M2+(aq)(M = Mn, Fe, Co, Ni) or with M(NH3)5(OH2)3+(aq)(M = Cr, Co, Rh, Ir), the partial molar volumes of the transition states display less than one-third of the variability of the partial molar volumes of the initial states as M is varied within each series.
T. W. Swaddle, J. Chem. Soc., Chem. Commun., 1982, 832 DOI: 10.1039/C39820000832
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