Issue 14, 1982

Kinetics of the pyrolsis of 1- methyl-1-vinyl-1 silacyclobutane; some observations on the stability of vinyl silyl radicals and silabutadienes

Abstract

Pyrolysis of the title compound to give ethene and a silabutadiene has the same Arrhenius parameters as pyrolysis of 1,1-dimethyl-1 silacycologutane whence the allylic stabillisation in a vinyl silyl radical is estimated to be ⩽29 kJ mol–1 some comments are also made on the stability of silabutadienses.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 806-807

Kinetics of the pyrolsis of 1- methyl-1-vinyl-1 silacyclobutane; some observations on the stability of vinyl silyl radicals and silabutadienes

I. M. T. Davidson, A. M. Fenton, P. Jackson and F. T. Lawrence, J. Chem. Soc., Chem. Commun., 1982, 806 DOI: 10.1039/C39820000806

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements