Sever metal oxides react with the system dimethyl sulphoxide–sulphur dioxide to give metal disulphates; in contrast with the spontaneous reaction of metals with the system no evidence is found for the involvement of metal–SO2– ion pairs, and direct conversion of oxide through sulphite is thought to occur.
B. Jeffreys, J. B. Gill and D. C. Goodall, J. Chem. Soc., Chem. Commun., 1982, 788 DOI: 10.1039/C39820000788
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