A novel synthesis of the isoquinoline alkaloids, (±)-xylopinine and (±)-laudanosine, has been developed via intra- and molecular nucleophilic addition, respectively, of an organosilicon compound to a carbon–nitrogen double bond.
S. Takano, H. Numata and K. Ogasawara, J. Chem. Soc., Chem. Commun., 1982, 769 DOI: 10.1039/C39820000769
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