Issue 13, 1982

Direct spectroscopic evidence for the formation of an asymmetric intermediate in the oxidation of alkenes by osmium tetraoxide

Abstract

1 H N.m.r. spectral investigation of the reaction of osmium tetraoxide, OsO4, with 1,1′-diphenylethene has shown, for the first time, direct evidence for the formation of an asymmetric intermediate which may be assigned as involving a cyclic four-membered ring species with an osmium–carbon bond.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 734-736

Direct spectroscopic evidence for the formation of an asymmetric intermediate in the oxidation of alkenes by osmium tetraoxide

M. Schröder and E. C. Constable, J. Chem. Soc., Chem. Commun., 1982, 734 DOI: 10.1039/C39820000734

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