Glycosyloxyselenation of tri-O-benzyl-D-glucal followed by oxidation and regiospecific syn-elimination of the resulting selenoxide offers, via an in situ generated keten acetal, a new method for the stereoselective construction of spiro-orthoesters associated with carbohydrate residues, as found in the orthosomycins.
G. Jaurand, J. Beau and P. Sinaÿ, J. Chem. Soc., Chem. Commun., 1982, 701 DOI: 10.1039/C39820000701
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...