The newly synthesized adenosylsulphonium ion, (2), undergoes a facile ring closure reaction in aqueous oxyanion buffers; in contrast, amine buffers effect an intermolecular dealkylation in competition with the lyate reaction.
P. J. Vasquez and J. K. Coward, J. Chem. Soc., Chem. Commun., 1982, 698 DOI: 10.1039/C39820000698
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