Issue 12, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

The N2F4⇌ 2NF2 equilibrium studied with a tunable infrared diode laser

Paul B. Davies,   Choon J. Kho,   Weng K. Leong  and  Wyn Lewis-Bevan  

Abstract

The enthalpy change for the N2F4⇌ 2NF2 equilibrium has been determined at temperatures between 50 and 200 °C and pressures between 5 and 26 Torr using an infrared diode laser to measure relative NF2 concentrations; using lines in the ν1 band of NF2to determine intensities and allowing for the finite degree of dissociation at the pressures used, a value for ΔH of 78 ± 6kJ mol–1 was calculated, in good agreement with previous determinations.

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Article information

DOI
https://doi.org/10.1039/C39820000690
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 690-691

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The N2F4⇌ 2NF2 equilibrium studied with a tunable infrared diode laser

P. B. Davies, C. J. Kho, W. K. Leong and W. Lewis-Bevan, J. Chem. Soc., Chem. Commun., 1982, 690 DOI: 10.1039/C39820000690

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