Issue 11, 1982

Asymmetric photopolymerisation in chiral crystals. An example of a chiral resolved monomer packing in two quasi-enantiomeric phases

Abstract

The ability of molecules, chiral by virtue of the presence of an s-butyl group, to display conformational polymorphism has been exploited for the performance of asymmetric syntheses of either sense on the same chiral molecule; this phenomenon is illustrated for the asymmetric solid-state polymerization of the monomer (R)-(–)-(1).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 584-587

Asymmetric photopolymerisation in chiral crystals. An example of a chiral resolved monomer packing in two quasi-enantiomeric phases

J. van Mil, L. Addadi, M. Lahav and L. Leiserowitz, J. Chem. Soc., Chem. Commun., 1982, 584 DOI: 10.1039/C39820000584

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