Issue 11, 1982

Binuclear platinum(II)–dppm acetylides and the formation of fluxional complexes of the type [Pt(η1-dppm)2(C[triple bond, length half m-dash]CR)2](dppm = Ph2PCH2PPh2)

Abstract

High-yield syntheses of two new types of dppm (PH2PCH2PPh2) complexes are described: (i) the fluxional complexes trans-[Pt(C[triple bond, length half m-dash]CR)2(η1-dppm)2], and (ii) the ‘face-to-face’ binuclear complexes [Pt2(C[triple bond, length half m-dash]CR)42-dppm)2](R = Ph or p-tolyl).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 581-583

Binuclear platinum(II)–dppm acetylides and the formation of fluxional complexes of the type [Pt(η1-dppm)2(C[triple bond, length half m-dash]CR)2](dppm = Ph2PCH2PPh2)

P. G. Pringle and B. L. Shaw, J. Chem. Soc., Chem. Commun., 1982, 581 DOI: 10.1039/C39820000581

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