Issue 10, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

X-Ray crystal structure of the pentagonal bipyramidal nickel(II) complex [NiII(L)(H2O)2](BF4)2 and the selective stabilisation of the nickel(I) oxidation state by a quinquedentate macrocyclic ligand

Christopher W. G. Ansell,   Jack Lewis,   Paul R. Raithby,   John N. Ramsden  and  Martin Schröder  

Abstract

The single crystal X-ray structure of the pentagonal bipyramidal nickel(II) complex [NiII(L)(H2O)2](BF4)2 involving the quinquedentate macrocyclic ligand L is reported; electrochemical reduction of a series of related nickel(II) complexes [NiII(L)X2](BF4)2 yields in solution d9 nickel(I) species.

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Article information

DOI
https://doi.org/10.1039/C39820000546
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 546-547

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X-Ray crystal structure of the pentagonal bipyramidal nickel(II) complex [NiII(L)(H2O)2](BF4)2 and the selective stabilisation of the nickel(I) oxidation state by a quinquedentate macrocyclic ligand

C. W. G. Ansell, J. Lewis, P. R. Raithby, J. N. Ramsden and M. Schröder, J. Chem. Soc., Chem. Commun., 1982, 546 DOI: 10.1039/C39820000546

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