Reaction of sodium oxide with alumina has produced a new sodium aluminate Na17Al5O16(monoclinic, space group Cm) and X-ray crystal structure determination has shown it to consist of discrete Al5O16 chains composed of five AlO4 tetrahedra sharing corners, with almost linear angles about the bridging oxygens.
M. G. Barker, P. G. Gadd and S. C. Wallwork, J. Chem. Soc., Chem. Commun., 1982, 516 DOI: 10.1039/C39820000516
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