Low temperature reductions of [Ru(CO)2(P–P)2][SbF6]2[P–P = Ph2PCH2PPh2(dppm) or (Ph2PCH2)2(dppe)] with NaHB(OEt)3 or LiHBEt3 afford the formyl complexes, [Ru(CHO)(CO)(P–P)]2X (X =[SbF6]–or [BEt4]–), which are fully characterised by spectroscopic means.
G. Smith and D. J. Cole-Hamilton, J. Chem. Soc., Chem. Commun., 1982, 490 DOI: 10.1039/C39820000490
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