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Issue 9, 1982
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1:1 Adducts of dimethyltin (IV) dichloride forming six-co-ordinated solids

Abstract

The crystal structures of the 1:1 adducts of dimethyltin (IV) dichloride with diphenylcyclopropenone and with 2, 6-dimethylpyridine (2,6-lutidine)N-oxide reveal dimer formation through bridging chlorine atoms to create six-co-ordination at tin, and the structure of the 1:1 salicylaldehyde adduct is reinterpreted in similar terms as an associated solid with bridging phenolic oxygen atoms; Mössbauer quadrupole splitting data, where available, corroborate the suggestion of six-co-ordination for the known 1:1 complexes.

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Article information


J. Chem. Soc., Chem. Commun., 1982, 475-476
Article type
Paper

1:1 Adducts of dimethyltin (IV) dichloride forming six-co-ordinated solids

S. Ng and J. J. Zuckerman, J. Chem. Soc., Chem. Commun., 1982, 475
DOI: 10.1039/C39820000475

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