Solutions of α-mercapto-ketone anions, generated from O-ethyl S-2-oxoethyl dithiocarbonates and piperidine, react with cyanamides to give 2-aminothiazoles with substituents on the heterocycle or the exo-nitrogen atom.
M. D. Brown, D. W. Gillon, G. D. Meakins and G. H. Whitham, J. Chem. Soc., Chem. Commun., 1982, 444 DOI: 10.1039/C39820000444
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