SCHEDULED MAINTENANCE:
Lithium methyl dithioacetate reacts with enones at low temperature via a selective 1,4-C-addition to give 5-oxodithioesters; further elaboration by thiophilic addition and alkylation furnishes masked 1,5-dicarbonyl compounds.
P. Metzer, J. Chem. Soc., Chem. Commun., 1982, 335 DOI: 10.1039/C39820000335
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