Issue 3, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

Stereochemistry of isoflavone reduction during the biosynthesis of (+)-and (–)-pterocarpans: 2H n.m.r. studies on the biosynthesis of (+)-pisatin and (–)-medicarpin

Stephen W. Banks,   Melanie J. Steele,   David Ward  and  Paul M. Dewick  

Abstract

2 H N.m.r. Spectroscopy has indicated the overall Z addition of hydrogen to the double bond of formononetin (3) during the bisosynthesis of (+)-(6aR, 11aR)-pisatin (6), in contrast with an E addition during production of (–)-(6aR, 11aR)-medicarpin (1).

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Article information

DOI
https://doi.org/10.1039/C39820000157
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 157-158

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Stereochemistry of isoflavone reduction during the biosynthesis of (+)-and (–)-pterocarpans: 2H n.m.r. studies on the biosynthesis of (+)-pisatin and (–)-medicarpin

S. W. Banks, M. J. Steele, D. Ward and P. M. Dewick, J. Chem. Soc., Chem. Commun., 1982, 157 DOI: 10.1039/C39820000157

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