Issue 2, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

The nature of ‘Pt(Ph2PCH2CH2PPh2).’ A platinum(I)–platinum(I) dimer containing bridging cyclometallated 1,2-bis(diphenylphosphino)-ethane; X-ray crystal structure

Dennis P. Arnold,   Martin A. Bennett,   Malcolm S. Bilton  and  Glen B. Robertson  

Abstract

Single-crystal X-ray structural analysis of a complex of empirical formula [pt(dppe)](dppe = Ph2PCH2CH2PPh2) formed by heating [Pt(OH)Me(dppe)]in methanol shows that it should be formulated as [Pt-µ-{o-C6H4P(Ph)CH2PPh2}]2 and that it contains cyclometallated dppe ligands bridging a Pt1–Pt1 bond.

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Article information

DOI
https://doi.org/10.1039/C39820000115
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 115-116

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The nature of ‘Pt(Ph2PCH2CH2PPh2).’ A platinum(I)–platinum(I) dimer containing bridging cyclometallated 1,2-bis(diphenylphosphino)-ethane; X-ray crystal structure

D. P. Arnold, M. A. Bennett, M. S. Bilton and G. B. Robertson, J. Chem. Soc., Chem. Commun., 1982, 115 DOI: 10.1039/C39820000115

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