Supported transition metals(Pt, Pd, Ru, Rh) and PdO and PtO2 catalyse the reaction M–CO + L → M–L + CO (L = isonitrile, group 5 donor ligand) and readily give complexes such as Mo(CO)2(PhCH2NC)4, Mn2(CO)9(C6H11NC), Ir4(CO)6(ButNC)6, and Re2(CO)8(PMePh2)2in high yield; the catalyst supports also show mild catalytic behaviour.
M. O. Albers, N. J. Coville and E. Singleton, J. Chem. Soc., Chem. Commun., 1982, 96 DOI: 10.1039/C39820000096
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