A new low co-ordination mode for nitrogen in a nitrido metal cluster: X-ray crystal structure of [Mo3(N)(O)(CO)4(η-C5H5)3]
Abstract
Heating [Mo2(CO)4(η-C5H5)2] with ethyl diazoacetate yields [Mo3(N)(O)(CO)4(η-C5H5)3], shown by X-ray diffarction to contain a nitrogen atom with T-Shaped co-ordination, bound to three molybdenum atoms.
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