Issue 1, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

Double insertion of a platinum nucleophile into a closo-carbaborane: molecular structures of 4,4-(Et3P)2-1,7-Me2-1,4,7-CPtCB5H5 and 1,1-(Et3P)2-6,6-(Et3P)2-4,5-Me2-1,4,5,6-PtC2PtB5H5

Geoffrey K. Barker,   Maria P. Garcia,   Michael Green,   F. Gordon A. Stone  and  Alan J. Welch  

Abstract

The carbaboranes closo-2,4-R2-2,4-C2B5H5(R = H or Me) react with [Pt2(µ-cod)(PEt3)4](cod = cycol-octa-1,5-diene) to afford the carbaplatinaboranes 4,4-(Et3P)2-1,7-R2-1,4,7-CPtCB5H5and 1,1-(Et3P)2-6,6-(Et3P)2-4,5-Me2-1,4,5,6-PtC2PtB5H5; the molecular structures of the two methyl derivatives have been established by X-ray diffraction.

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Article information

DOI
https://doi.org/10.1039/C39820000046
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 46-48

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Double insertion of a platinum nucleophile into a closo-carbaborane: molecular structures of 4,4-(Et3P)2-1,7-Me2-1,4,7-CPtCB5H5 and 1,1-(Et3P)2-6,6-(Et3P)2-4,5-Me2-1,4,5,6-PtC2PtB5H5

G. K. Barker, M. P. Garcia, M. Green, F. G. A. Stone and A. J. Welch, J. Chem. Soc., Chem. Commun., 1982, 46 DOI: 10.1039/C39820000046

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