Issue 11, 1981

Intramolecular [2 + 2] photoaddition of a 1,7-diene

Abstract

Intramolecular photoaddition of the 1,7-diene system in 4-(1,5-dimethylhex-4-enyl)cyclohex-2-enone (3) yielded, inter alia, two ketones containing the tricyclo[5.3.1.05,11]undecan-8-one system. The structure and stereochemistry of these ketones has been determined from X-ray crystallographic analyses of suitable derivatives.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1981, 1473-1480

Intramolecular [2 + 2] photoaddition of a 1,7-diene

K. D. Croft, E. L. Ghisalberti, P. R. Jefferies, A. D. Stuart, C. L. Raston and A. H. White, J. Chem. Soc., Perkin Trans. 2, 1981, 1473 DOI: 10.1039/P29810001473

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