The σ˙ scale of radical stabilization derived from the thermal decomposition of substituted dibenzyl mercurials is compared with other proposed scales. By using the σ˙ scale, the parameter ρ˙ can be used as a probe for the amount of radical character developed or destroyed in the transition state of a free radical reaction.
S. Dinçtürk and R. A. Jackson, J. Chem. Soc., Perkin Trans. 2, 1981, 1127 DOI: 10.1039/P29810001127
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