SCHEDULED MAINTENANCE
The synthesis and structures of π-allyl palladium complexes prepared from vitamins D2 and D3 and from ergosterol, 7,8-didehydrocholesterol, and 3-epi-cholesterol are described. The mechanism of palladisation is discussed as well as the transformation of the complexes into conjugated trienes or allylic alcohols.
C. Mahé, H. Patin, M. Van Hulle and D. H. R. Barton, J. Chem. Soc., Perkin Trans. 1, 1981, 2504 DOI: 10.1039/P19810002504
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