Treatment of benzyl methyl ether with n-butyl-lithium–tetramethylenediamine in hexane gave benzylic-lithiation, without ortho-lithiation or a Wittig type rearrangement. The benzylic-lithiated benzyl methyl ether was then allowed to react with benzophenone, 4-methoxybenzophenone, butyl bromide, ethyl phenylacetate, and 4-chlorobenzophenone.
M. K. Yeh, J. Chem. Soc., Perkin Trans. 1, 1981, 1652 DOI: 10.1039/P19810001652
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