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The products of solvolysis of 2β-halogeno-derivatives of 7-methyl-7-azabicyclo[2.2.1]heptane, 8-methyl-8-azabicyclo[3.2.1]octane,9-methyl-9-azabicyclo-[4.2.1]- and -[3.3.1]-nonane, and 7-methyl-7-azabicyclo[3.2.1]-octane, have been isolated and characterised. Solvolytic rearrangement of 2-bromotropinone to a 4-hydroxy-tropan-6-one is also described.
J. W. Bastable, A. J. Cooper, I. R. Dunkin, J. D. Hobson and W. D. Riddell, J. Chem. Soc., Perkin Trans. 1, 1981, 1339 DOI: 10.1039/P19810001339
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