Issue 0, 1981

Asymmetric induction in the reduction of β-oxosulphoximides by sodium borohydride

Abstract

Optically active β-oxosulphoximides have been prepared by reaction of optically active α-metallated NS-dimethyl-S-phenylsulphoximide with carboxylic esters. Their reduction by sodium borohydride is stereoselective, the extent of asymmetric synthesis (up to 50%) depending on steric factors.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1981, 1109-1111

Asymmetric induction in the reduction of β-oxosulphoximides by sodium borohydride

R. Annunziata, M. Cinquini and F. Cozzi, J. Chem. Soc., Perkin Trans. 1, 1981, 1109 DOI: 10.1039/P19810001109

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