Reaction of 4-hydroxy-2-quinolone with geranyl chloride gave the geranyl ether (5a), the C-geranyl derivatives (6) and (7), and the vinylhexenyl derivative (8). The geranyl ether was converted into bucharaine (1) by selective hydroxylation and via mono-epoxidation.
M. F. Grundon, V. N. Ramachandran and M. E. Donnelly, J. Chem. Soc., Perkin Trans. 1, 1981, 633 DOI: 10.1039/P19810000633
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