The title compound (1) has been prepared from gibberellic acid; its addition to a fermentation of G. fujikuroi led to the accumulation of ent-kaurene, and hence suggested that it inhibited the biosynthetic oxidation of kaurene. Compound (1) also retards the conversion of gibberellin A12 aldehyde (25) into gibberellins A12(26) and A43(21) by a plant enzyme system.
K. Boulton and B. E. Cross, J. Chem. Soc., Perkin Trans. 1, 1981, 427 DOI: 10.1039/P19810000427
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