Issue 0, 1981

Formation of diphenyl ethers from cyclohexa-2,5-dienones via 4-phenoxy-4-(1-alkoxy)cyclohexa-2,5-dienones as probable intermediates

Abstract

Acid-catalysed reactions of the cyclohexa-2,5-dienones (3) and (14) with phenol afford diphenyl ethers. Quinol ethers are considered to be intermediates in these reactions, with aromatisation of the cyclohexa-2,5-dienone ring by loss of the 4-(1-alkoxy) side-chain as an aldehyde constituting the driving force.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1981, 303-306

Formation of diphenyl ethers from cyclohexa-2,5-dienones via 4-phenoxy-4-(1-alkoxy)cyclohexa-2,5-dienones as probable intermediates

M. Karhu, J. Chem. Soc., Perkin Trans. 1, 1981, 303 DOI: 10.1039/P19810000303

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