SCHEDULED MAINTENANCE
The title compound, a simple AB ring moiety of withaferin A, and its seven isomers, were synthesized via octahydro-4a-hydroxy-5-(phenylthio)-8a-methylnaphthalen-1(2H)-ones [(5a) and (5b)]. The key steps in the synthesis involve either 1,2-phenylthio-migration, or dehydration reactions of (5a) and (5b).
M. Hirayama, S. Fukatsu and N. Ikekawa, J. Chem. Soc., Perkin Trans. 1, 1981, 88 DOI: 10.1039/P19810000088
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