Photoelectron spectra of some halogenomethanes
Abstract
The He I and He II photoelectron spectra of CBrCl3, CHBrCl2, CHBr2Cl, CH2BrCl, CHFCl2 and CHF2Cl have been recorded with low and high resolutions. Correlation with assignments for other halogenated methanes, comparison of He II/He I intensities and vibrational fine-structure analysis allowed all the systems with ionization energies up to 24 eV to be assigned.