Issue 9, 1981
From the journal:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Generation of chlorine dioxide from ClO –2 by pulse radiolysis

Trygve E. Eriksen,   Johan Lind  and  Gábor Merényi  

Abstract

The yield of ClO.2 in irradiated aqueous solutions of NaClO2 has been determined by pulse and steady-state radiolyses. The yield was found to be dependent on ClO–2 concentration but independent of pH. The solvated electron was found to react with ClO–2 with a rate constant (2.5 ± 0.5)× 109 S–1 mol–1 dm3 to yield ClO–. In its reaction with ClO–2 the OH. radical was found to produce two species; ClO.2 and an OH. adduct. At sufficiently high ClO–2 concentrations the adduct reacts with ClO–2 producing further ClO.2.

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Article information

DOI
https://doi.org/10.1039/F19817702115
Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1981,77, 2115-2123

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Generation of chlorine dioxide from ClO–2 by pulse radiolysis

T. E. Eriksen, J. Lind and G. Merényi, J. Chem. Soc., Faraday Trans. 1, 1981, 77, 2115 DOI: 10.1039/F19817702115

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