The relative rates of the two unimolecular decomposition channels have been determined as a function of pressure at 542.2 °C. These have been compared with RRKM calculations based on a step-ladder model for collisional energy transfer. The results are consistent with an average value of ΔE≈ 12 kJ mol–1.
I. M. Bailey and H. M. Frey, J. Chem. Soc., Faraday Trans. 1, 1981, 77, 709 DOI: 10.1039/F19817700709
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