The two title complexes with free double bonds have been used as substrates in the olefin-metathesis reaction. The reaction with [Fe(cot)(CO)3] produces a dimeric complex with a new pentacyclic carbon skeleton; that with [Fe(cht)(CO)3] leads to the dimeric compound tetracarbonylbis(cycloheptadienyl)di-iron, whose stereochemistry is discussed.
H. A. Bockmeulen and A. W. Parkins, J. Chem. Soc., Dalton Trans., 1981, 262 DOI: 10.1039/DT9810000262
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