Synthesis and X-ray characterization of the novel [Rh10S(CO)10(µ-CO)12]2– anion; a bicapped square-antiprismatic cluster containing an interstitial sulphur atom
Abstract
The anion [Rh10S(CO)22]2–, obtained by slow decomposition of [Rh6(CO)14(SCN)2]2– in tetrahydrofuran, has been investigated by X-ray diffraction; it contains a bicapped square-antiprismatic metal atom cluster, with an interstitial sulphur atom.
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