The novel compounds trans-(CF3)2Pd(PMe3)2 and (CF3)2Ni(PMe3)3 have been prepared by co-condensation of palladium and nickel with trifluoromethyl radicals; initially the thermally unstable unsaturated alkyls Pd(CF3)2 and Ni(CF3)2 were prepared which were subsequently stabilized by trapping with trimethylphosphine at low temperature.
D. W. Firsich and R. J. Lagow, J. Chem. Soc., Chem. Commun., 1981, 1283 DOI: 10.1039/C39810001283
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