Issue 23, 1981

On anchimerically assisted homolysis via sulphide functions

Abstract

In contrast to O–O fission, anchimeric assistance from sulphide functions in the rate of unimolecular fission of the N–O bond is only marked for heterolysis reactions; analogous homolyses are very much less accelerated, although bridged radical intermediates are involved.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 1238-1239

On anchimerically assisted homolysis via sulphide functions

A. J. Lawson, J. Chem. Soc., Chem. Commun., 1981, 1238 DOI: 10.1039/C39810001238

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