The two thiazepinone-containing peptides (5) and (7), as well as the β-hydroxyvaline peptide (3), have been synthesised and tested as substrates for isopenicillin N synthesis in a cell-free extract from Cephalosporium acremonium; none of these compounds behaved as substrates, in contradiction to a recent proposal.
G. Bahadur, J. E. Baldwin, T. Wan, M. Jung, E. P. Abraham, J. A. Huddleston and R. L. White, J. Chem. Soc., Chem. Commun., 1981, 1146 DOI: 10.1039/C39810001146
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