The oxidative cleavage of disulphide bonds to form the sulphonic acid derivatives is shown to be an important reaction of AuX4–(X = Cl, Br) with proteins and peptides; the implications of this reaction for the toxicity of gold compounds are discussed.
P. L. Witkiewicz and C. F. Shaw, J. Chem. Soc., Chem. Commun., 1981, 1111 DOI: 10.1039/C39810001111
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